Improving charge injection in organic thin-film transistors with thiol-based self-assembled monolayers

Organophosphonate self-assembled monolayers for gate dielectric surface modification of pentacene-based organic thin-film transistors: a comparative study.

Organic thin-film transistors using pentacene as the semiconductor were fabricated on silicon. A series of phosphonate-based self-assembled monolayers (SAMs) was used as a buffer between the silicon dioxide gate dielectric and the active pentacene channel region. Octadecylphosphonate, (quarterthiophene)phosphonate, and (9-anthracene)phosphonate SAMs were examined. Significant improvements in th...

Injection-modulated polarity conversion by charge carrier density control via a self-assembled monolayer for all-solution-processed organic field-effect transistors

We demonstrated modulation of charge carrier densities in all-solution-processed organic field-effect transistors (OFETs) by modifying the injection properties with self-assembled monolayers (SAMs). The all-solution-processed OFETs based on an n-type polymer with inkjet-printed Ag electrodes were fabricated as a test platform, and the injection properties were modified by the SAMs. Two types of...

Controlling charge injection in organic field-effect transistors using self-assembled monolayers.

We have studied charge injection across the metal/organic semiconductor interface in bottom-contact poly(3-hexylthiophene) (P3HT) field-effect transistors, with Au source and drain electrodes modified by self-assembled monolayers (SAMs) prior to active polymer deposition. By using the SAM to engineer the effective Au work function, we markedly affect the charge injection process. We systematica...

Modifying Charge Carrier Injection Using Self-Assembled Monolayers in Organic Field-Effect Transistors

Modification of gold source and drain electrodes by self-assembled monolayer in staggered n- and p-channel organic thin film transistors

We report on the effect of the deposition of self-assembled monolayers (SAMs) on the source and drain electrodes on the contact resistance and mobility in organic thin film transistors (OTFTs). Ultraviolet photoelectron spectroscopy (UPS) shows a variation of the work function of the electrodes depending on the SAM. OTFTs were fabricated with solution processible Polyera ActivInk N1400, TIPS-pe...